AUDIT — h14-protein-replacement (STRC Protein Replacement Therapy)

  • Tier: C · mech 2 / deliv 1 / misha_fit 3 · next_step: No delivery route
  • lit_audit before: deferred (2026-04-23)
  • lit_audit after: partial, 2 blockers
  • Grounding: GROUNDING/hypc-h14-protein-replacement.md
  • Proportionality: C-tier, no scripts. Short pass — but it surfaced a real contradiction, so the writeup is longer than the retrieval.

Parameter-provenance table

#ClaimValueSourceLocal sources/lit/Status
1STRC full-length mass~220 kDaderived from 1775 aa + heavy N-glycosylation✅ derived, internally coherent
2Mini-STRC mass (700–1775)~115 kDaderived, 1076 aa✅ derived
3Diffusion coefficient at 115 kDaD ≈ 2–4 µm²/s”Stokes-Einstein” — method named, no citation, no radius given❌ UNSOURCED ESTIMATE
4Perilymph length~5 mmanatomical🔶 uncited but textbook; cf. Salt 2001’s human ST ~28.5 mm
5Distribution time to all OHC rows”hours”computed from #3 + #4🔶 inherits #3
6ERT scale feasibilityqualitative”modern CHO/HEK systems”⚙ qualitative
7N-glycosylation requirementqualitative[[STRC N-Glycosylation Analysis]] (in-vault)
8RWM permeability — the step the kill actually turns onnever computedSalt & Ma 2001 is already ✅ in sources/lit/ and was never applied here2001-salt-ma-quantification-rwm-permeability.md❌ NOT APPLIED

Finding 1 — the hub’s kill contradicts the note’s own conclusion

Hub: next_step: No delivery route.

Note, line 64:

Diffusion modeling — Stokes-Einstein: at 115 kDa, D ≈ 2-4 µm²/s in aqueous. Perilymph ~5 mm long. Time to diffuse to all OHC rows: hours. Feasible.

The note concludes distribution is feasible in hours; the hub kills the hypothesis for having no delivery route. These are almost certainly about different steps — crossing the round-window membrane into perilymph versus diffusing along perilymph once inside — and the reconciliation is probably straightforward. But it is written down nowhere. As the vault stands, a reader cannot tell whether h14 was killed on evidence or on an unstated assumption, and lit_audit: deferred meant nobody had ever asked.

For a C/D-tier hypothesis the audit’s whole job is confirming the kill rests on sourced evidence. Here it rests on an unrecorded inference.

Finding 2 — the kill is quantifiable from a paper the vault already owns

sources/lit/2001-salt-ma-quantification-rwm-permeability.md (type: lit) was retrieved, MinerU-parsed, and closed to ✅ during the h09 audit. Line 44:

| RWM permeability (TMPA) | 1.9 × 10⁻⁸ | cm/s | Guinea pig; TMPA ion MW ~166 Da |

with the paper’s own endorsed MW-scaling method worked through at lines 61–62. This is precisely the RWM-crossing step that h14’s kill turns on, and it has never been applied to h14.

Extending the same MW^−1/3 scaling to mini-STRC at 115 kDa would give P ≈ 2.2 × 10⁻⁹ cm/s, ~10× below the TMPA ion — i.e. it would likely support the kill. I record that as an illustration of the available calculation, not as a result: Salt & Ma measured a 166 Da ion, and pushing Stokes–Einstein across nearly three decades of molecular weight onto a heavily glycosylated 115 kDa glycoprotein is far outside what that paper supports. Hardening that number into a “value” is exactly what §0c exists to prevent, and I am not doing it.

The finding is structural, not numerical: h14’s kill can be grounded in literature the vault already holds, and nobody has done it. That is a cheap concrete task, not a literature gap — which is why h14 lands on partial rather than not-modelable.

Cross-hypothesis note: this makes Salt & Ma 2001 load-bearing for h09 (ototopical ear drop) and h14 (intratympanic protein). One paper, two hypotheses, one already using it properly.

Verdict

lit_audit: partial · lit_audit_date: 2026-08-21 · 2 blockers

lit_audit: partial
lit_audit_date: 2026-08-21
lit_audit_blockers:
  - "Kill rationale is unrecorded and contradicts the hypothesis note. Hub says next_step 'No delivery route'; STRC Protein Replacement Therapy.md:64 concludes intracochlear distribution is 'Feasible' in hours, and line 50 argues mini-STRC at 115 kDa is smaller than several approved ERT proteins. The two are probably about different steps (crossing the round-window membrane vs diffusing along perilymph once inside), but that reconciliation is written down nowhere. A reader cannot currently tell whether h14 was killed on evidence or on an unstated assumption. Next step: state the kill's actual step and basis in the hub."
  - "Diffusion coefficient D = 2-4 um^2/s at 115 kDa (STRC Protein Replacement Therapy.md:64) — UNSOURCED ESTIMATE. Method is named (Stokes-Einstein) but no citation and no hydrodynamic radius is given, and it is load-bearing for the 'Feasible' half of the contradiction above. Related and more useful: the RWM-crossing step the kill actually turns on is quantifiable from a paper the vault ALREADY OWNS and has never applied here — sources/lit/2001-salt-ma-quantification-rwm-permeability.md (type: lit), RWM permeability 1.9e-8 cm/s for the 166 Da TMPA ion, with the paper's own endorsed MW-scaling method at lines 61-62. Applying it to 115 kDa would likely SUPPORT the kill, but the extrapolation spans ~3 decades of molecular weight onto a heavily glycosylated protein and must be flagged as an extrapolation, not a measurement."

Ranking delta

C-tier HELD. No mech/deliv/misha_fit change. See RANKING-DELTA.md.